When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | c-C6H11O2_Rowley(1991)_298K_210-300nm.txt |
NAME: | cyclohexylperoxy radical |
FORMULA: | c-C6H11O2 |
AUTHOR(YEAR): | Rowley(1991) |
T: | 298K |
λ: | 210-300nm |
BIBLIOGRAPHY: |
D.M. Rowley, P.D. Lightfoot, R. Lesclaux, and T.J. Wallington, "UV spectrum and self-reaction kinetics of the cyclohexylperoxy radical",
J. Chem. Soc. Faraday Trans. 87, 3221-3226 (1991);
DOI: 10.1039/FT9918703221
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COMMENTS: | Flash photolysis technique coupled with UV absorption spectrometry; photolysis of flowing c-C6H12/Cl2/O2/N2 mixtures
Original values:Calibration against the well established methylperoxy radical spectrum, using σ(CH3O2) = 4.55 x 10-18 cm2 molecule-1 at 240 nm of F. Simon, W. Schneider, and G.K. Moortgat, "UV-absorption spectrum of the methylperoxy radical and the kinetics of its disproportionation reaction at 300 K", Int. J. Chem. Kinet. 22, 791-813 (1990);DOI: 10.1002/kin.55022080 |
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